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鐘離君柏墓出土彩繪陶器顏料的光譜分析
摘要：利用拉曼光譜結(jié)合X射線衍射物相檢測(cè)方法,對(duì)安徽蚌埠雙墩春秋中晚期鐘離君柏墓出土彩繪陶器顏料的物相結(jié)構(gòu)進(jìn)行了分析測(cè)定.結(jié)果表明,陶器表面的紅色、黃色和黑色顏料皆保存較好,未發(fā)生明顯變化,分別是無(wú)機(jī)礦物朱砂(HgS)和針鐵礦(α-FeO(OH))及炭黑.同時(shí),拉曼光譜與X射線衍射分析的結(jié)果都顯示紅色顏料朱砂的組成物相單一,不含天然朱砂的伴生礦物石英,且其晶粒尺寸可能在納米范圍,應(yīng)是由人工合成或經(jīng)過(guò)古人的加工、純化處理.針鐵礦的發(fā)現(xiàn)表明春秋時(shí)期該礦物己被用作黃色顏料,這是目前己知的針鐵礦作為黃顏料使用的最早的實(shí)例.Abstract：Based on the analysis of Raman spectroscopy and XRD methods, the structures of different pigments on the painted pottery from the Monarch Bai Tomb of Zhongli State in the middle and late Spring and Autumn period at Shungdun Village, Bengbu City, Anhui Province were analyzed. The result shows that all the pigments, including red, yellow and black pigments, have been well preserved, and these three pigments were identified as cinnabar, goethite and carbon black respectively. Both Raman spectroscopy and XRD analysis show that the crystal composition of red pigments, cinnabar, is very pure without quartz crystal, the associated crystal of natural cinnabar, and at the same time the crystal size of cinnabar is possibly at the nanometer scale It suggests that this red pigments perhaps were a synthetic material or processed and purified by our ancestors. The dis-covery of goethite shows that this mineral has been used as pigments as early as in the Spring and Autumn period. This is the earliest example that goethite was used as yellow pigments. 作者： 楊玉璋[1] 張居中[1] 左健[2] 闞緒杭[3] 周群[3] Author： YANG Yu-zhang[1] ZHANG Ju-zhong[1] ZUO Jian[2] KAN Xu-hang[3] ZHOU Qun[3] 作者單位： 中國(guó)科學(xué)技術(shù)大學(xué)科技史與科技考古系,安徽,合肥,230026中國(guó)科學(xué)技術(shù)大學(xué)合肥微尺度物質(zhì)科學(xué)國(guó)家實(shí)驗(yàn)室(籌),安徽,合肥,230026安徽省文物考古研究所,安徽,合肥,230061 期 刊： 光譜學(xué)與光譜分析 ISTICEISCIPKU Journal： SPECTROSCOPY AND SPECTRAL ANALYSIS 年，卷(期)： 2010, 30(4) 分類(lèi)號(hào)： P575.4 K876.3 關(guān)鍵詞： 彩繪陶 顏料 拉曼光譜 X射線衍射 Keywords： Painted pottery Pigments Raman spectroscopy XRD 機(jī)標(biāo)分類(lèi)號(hào)： TQ1 O41 機(jī)標(biāo)關(guān)鍵詞： 出土 彩繪 陶器顏料 光譜分析 Spring and Autumn period Raman spectroscopy 針鐵礦 射線衍射 拉曼光譜 analysis nanometer scale quartz crystal black pigments 朱砂 物相 礦物 yellow crystal size carbon black 春秋中晚期 基金項(xiàng)目： 國(guó)家自然科學(xué)基金，中國(guó)科學(xué)院科研啟動(dòng)專(zhuān)項(xiàng)資金項(xiàng)目 鐘離君柏墓出土彩繪陶器顏料的光譜分析[期刊論文] 光譜學(xué)與光譜分析 --2010, 30(4)楊玉璋 張居中 左健 闞緒杭 周群利用拉曼光譜結(jié)合X射線衍射物相檢測(cè)方法,對(duì)安徽蚌埠雙墩春秋中晚期鐘離君柏墓出土彩繪陶器顏料的物相結(jié)構(gòu)進(jìn)行了分析測(cè)定.結(jié)果表明,陶器表面的紅色、黃色和黑色顏料皆保存較好,未發(fā)生明顯變化,分別是無(wú)機(jī)礦物朱砂(HgS...【鐘離君柏墓出土彩繪陶器顏料的光譜分析】相關(guān)文章：
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